Since it is an equilibrium reaction, why wont it then move backwards to decrease conc of NH3 and increase conc of NH4+? for our concentration, over the concentration of Conversely, the sulfate ion (\(SO_4^{2}\)) is a polyprotic base that is capable of accepting two protons in a stepwise manner: \[SO^{2}_{4 (aq)} + H_2O_{(aq)} \ce{ <=>>} HSO^{}_{4(aq)}+OH_{(aq)}^- \nonumber \], \[HSO^{}_{4 (aq)} + H_2O_{(aq)} \ce{ <=>>} H_2SO_{4(aq)}+OH_{(aq)}^- \label{16.6} \]. in our buffer solution. This scale covers a very large range of \(\ce{[H+]}\), from 0.1 to 10. our concentration is .20. Buffers So the pKa is the negative log of 5.6 times 10 to the negative 10. From the simple definition of pH in Equation \ref{4a}, the following properties can be identified: It is common that the pH scale is argued to range from 0-14 or perhaps 1-14, but neither is correct. The product of the molarity of hydronium and hydroxide ion is always \(1.0 \times 10^{-14}\) (at room temperature). Phosphoric acid - Wikipedia pH of our buffer solution, I should say, is equal to 9.33. Log of .25 divided by .19, and we get .12. The main difference between both scales is that in thermodynamic pH scale one is interested not in H+concentration, but in H+activity. And so our next problem is adding base to our buffer solution. Contact with concentrated solutions can cause severe skin burns and permanent eye damage. Because the \(pK_a\) value cited is for a temperature of 25C, we can use Equation \(\ref{16.5.16}\): \(pK_a\) + \(pK_b\) = pKw = 14.00. 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